Welcome Dandegyrecorder. I have some slightly different advice which by no means invalidates Mexi's (I have him to thank for introducing me after all

):
If you prefer to get a good background of a band and a sense of progression from early rougher work to later polished work, just go chronologically. "Music for Nitrous Oxide" is a great release and so suitably weird and dark, then you can go from there as more and more they bring the 'light' in as it were, giving their music more breathing space, less to no lofi fuzz, wider instrumentation and more I guess you'd say sublime/divine aesthetics and moods. I'd also suggest reading some interviews with them if you're like me and enjoy that kind of background.
If you prefer to immediately dive in on the deep end and experience their best work, listen to "The Tired Sounds of" and then jump to "And their Refinement of the Decline." Those albums are generally considered masterpieces of the ambient world (or indeed the world of music!) Then just work your way around their discography afterwards. If you preferred Tired Sounds go earlier straight away, particularly with "Avec Laudenum" or "The Ballasted Orchestra"; if you preferred Refinement look at their modern live show stuff (I highly recommend E7 for instance and am hoping it makes the next release) or indeed "A Winged Victory for the Sullen" too as I see that project of one of the members (Adam Wiltzie) to be a sibling of Refinement's sound.
Finally as I don't know whether you are an ambient/drone listener: Give this music your concentration and it will reward you with manifold details and mental images. Or if you find it boring/too slow, no problem. Keep it on, and let it sink in while you do something else. It will click eventually, without you forcing it to. Or it won't, and you'll know it's not for you
![Happy :]](./images/smilies/icon_grin.gif)
Have fun!